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. 2003 Apr 7:(7):832-3.
doi: 10.1039/b212405j.

A reductive recycle strategy for the facile synthesis of molybdenum(VI) alkylidyne catalysts for alkyne metathesis

Wei Zhang  1 , Stefan Kraft, Jeffrey S Moore
Affiliations

A reductive recycle strategy for the facile synthesis of molybdenum(VI) alkylidyne catalysts for alkyne metathesis

Wei Zhang et al. Chem Commun (Camb). .

Abstract

A convenient synthesis of trisamido molybdenum(VI) alkylidyne complexes has been developed, in which the key step is the addition of a geminal dichloride to a trisamido molybdenum(III) complex in the presence of magnesium to continuously recycle unwanted side product 4, selectively generating the desired alkylidyne complexes in high yield.

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