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. 2003 Jul 11;68(14):5742-5.
doi: 10.1021/jo030098a.

Direct electrophilic diamination of functionalized alkenes without the use of any metal catalysts

Dianjun Chen  1 , Cody Timmons, Han-Xun Wei, Guigen Li
Affiliations

Direct electrophilic diamination of functionalized alkenes without the use of any metal catalysts

Dianjun Chen et al. J Org Chem. .

Abstract

A new direct electrophilic diamination reaction of alpha,beta-unsaturated ketones and esters has been established without the use of any metal catalysts. Three types of nitriles (CH(3)CN, CH(3)CH(2)CN, and CH(3)CH(2)CH(2)CN) were employed as nucleophilic nitrogen sources. A new mechanism has also been proposed to explain the resulting regio- and stereoselectivity.

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