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. 2003 Aug 21;32(6):1227-34.
doi: 10.1016/s0731-7085(03)00217-6.

Voltammetric investigation of diethylstilbestrol

Inci Biryol  1 , Bülent Salci, Ender Erdik
Affiliations

Voltammetric investigation of diethylstilbestrol

Inci Biryol et al. J Pharm Biomed Anal. .

Abstract

In this work electrooxidation of diethylstilbestrol (DES) was investigated by cyclic voltammetry (CV) and differential pulse voltammetry (DPV) using a glassy carbon (GC) electrode. It was statistically shown that both methods could be used for the determination of DES in the concentration range of 2 x 10(-5)-6 x 10(-4) M by CV and 1 x 10(-5)-1 x 10(-3) M in methanol (MeOH) and 4 x 10(-5)-6 x 10(-4) M in acetonitrile (ACN) by DPV and both of the methods could be applied to human serum. A mechanism was proposed about the electrooxidation of this substance.

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