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. 2003 Sep 3;125(35):10538-9.
doi: 10.1021/ja0303844.

A convenient method for the preparation of inverted tert-alkyl carboxylates from chiral tert-alcohols by a new type of oxidation-reduction condensation using 2,6-dimethyl-1,4-benzoquinone

Teruaki Mukaiyama  1 , Taichi Shintou, Kentaro Fukumoto
Affiliations

A convenient method for the preparation of inverted tert-alkyl carboxylates from chiral tert-alcohols by a new type of oxidation-reduction condensation using 2,6-dimethyl-1,4-benzoquinone

Teruaki Mukaiyama et al. J Am Chem Soc. .

Abstract

Oxidation-reduction condensation using in situ-formed alkoxydiphenylphosphines, 2,6-dimethyl-1,4-benzoquinone, and carboxylic acids provided a new and efficient method for the preparation of inverted tert-alkyl carboxylates from various chiral tertiary alcohols.

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