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. 2003 Oct 8;125(40):12078-9.
doi: 10.1021/ja037072l.

Cyclohexane and benzene amination by catalytic nitrene insertion into C-H bonds with the copper-homoscorpionate catalyst TpBr3CuNCMe

M Mar Díaz-Requejo  1 , Tomás R Belderraín, M Carmen Nicasio, Swiatoslaw Trofimenko, Pedro J Pérez
Affiliations

Cyclohexane and benzene amination by catalytic nitrene insertion into C-H bonds with the copper-homoscorpionate catalyst TpBr3CuNCMe

M Mar Díaz-Requejo et al. J Am Chem Soc. .

Abstract

The complex TpBr3Cu(NCMe) catalyzes, at room temperature, the insertion of a nitrene group from PhINTs into the carbon-hydrogen bond of cyclohexane and benzene, as well as into the primary C-H bonds of the methyl groups of toluene and mesitylene, in moderate to high yield.

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