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. 2003 Oct;59(Pt 10):M381-3.
doi: 10.1107/s0108270103016755. Epub 2003 Sep 16.

Tris(3,5-dimethyl-1H-pyrazole-1-thiocarboxamidato-kappa(2)N(2),N)cobalt(III)

Zeljko K Jaćimović  1 , Zoran D Tomić, Gerald Giester, Vukadin M Leovac
Affiliations

Tris(3,5-dimethyl-1H-pyrazole-1-thiocarboxamidato-kappa(2)N(2),N)cobalt(III)

Zeljko K Jaćimović et al. Acta Crystallogr C. 2003 Oct.

Abstract

In the crystal structure of the title complex, [Co(C(6)H(8)N(3)S)(3)], the Co(III) atom is octahedrally coordinated by three monodeprotonated bidentate 3,5-dimethyl-1H-pyrazole-1-thiocarboxamide ligands with two thiocarboxamide N atoms in axial positions. The asymmetric unit contains two molecules (A and B) and these molecules are arranged in chains in an alternating fashion connected by N-H...S interactions.

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