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. 2003 Nov 3;42(22):6968-70.
doi: 10.1021/ic035080x.

Copper hydroperoxo species activated by hydrogen-bonding interaction with its distal oxygen

Syuhei Yamaguchi  1 , Shigenori Nagatomo, Teizo Kitagawa, Yasuhiro Funahashi, Tomohiro Ozawa, Koichiro Jitsukawa, Hideki Masuda
Affiliations

Copper hydroperoxo species activated by hydrogen-bonding interaction with its distal oxygen

Syuhei Yamaguchi et al. Inorg Chem. .

Abstract

A novel copper(II)[bond]OOH complex with functional ligand that can form a hydrogen bond with the distal oxygen of hydroperoxide has been designed and prepared as a structural/functional model of dopamine beta-hydroxylases, whose spectroscopic characterization and decomposition rates have indicated that the hydroperoxide is activated through the hydrogen-bonding interaction with the distal oxygen.

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