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. 2003 Nov 5;125(44):13314-5.
doi: 10.1021/ja0372661.

Constructing a stable carbene with a novel topology and electronic framework

Patrick Bazinet  1 , Glenn P A Yap, Darrin S Richeson
Affiliations

Constructing a stable carbene with a novel topology and electronic framework

Patrick Bazinet et al. J Am Chem Soc. .

Abstract

The perimidine skeleton provides a framework for the isolation of a novel, stable carbene possessing a unique molecular architecture and electronic structure. The remarkable steric environment and exceptional electron-donating ability for the carbene-carbon are revealed through structural and spectroscopic characterization of the parent carbene and two sterically encumbered rhodium-carbene complexes, L2RhCl{C[NCH(CH3)2]2(C10H6)} (5 L2 = COD; 6 L = CO).

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