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. 2003 Oct 7:(19):2414-5.
doi: 10.1039/b308668b.

Copper(II)-catalysed aerobic oxidation of primary alcohols to aldehydes

Patrick Gamez  1 , Isabel W C E Arends, Jan Reedijk, Roger A Sheldon
Affiliations

Copper(II)-catalysed aerobic oxidation of primary alcohols to aldehydes

Patrick Gamez et al. Chem Commun (Camb). .

Abstract

[CuBr2(2,2'-bipyridine)] catalyses the selective and very mild aerobic oxidation of primary alcohols to aldehydes in acetonitrile:water (2:1) in the presence of 2,2,6,6-tetramethylpiperidinyl-1-oxy (TEMPO) and a base as cocatalysts.

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