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. 2003 Oct 7:(19):2432-3.
doi: 10.1039/b307172n.

Self-asssembly of a molecular M8L12 cube having S6 symmetry

Zöe R Bell  1 , Lindsay P Harding, Michael D Ward
Affiliations

Self-asssembly of a molecular M8L12 cube having S6 symmetry

Zöe R Bell et al. Chem Commun (Camb). .

Abstract

Reaction of the bis-bidentate ligand L1, having two bidentate pyrazolyl-pyridine termini, with Co(II) or Zn(II) results in formation of the complexes [M8(L1)12]X16 (X = perchlorate or tetrafluoroborate); [Zn8(L1)2](ClO4)16 has been structurally characterised and is a cube with a metal ion at each corner, a bridging ligand along each edge, and an anion in the central cavity.

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