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. 2003 Oct 7:(19):2474-5.
doi: 10.1039/b306683e.

Bidentate ligands formed by self-assembly

Vincent F Slagt  1 , Piet W N M van Leeuwen, Joost N H Reek
Affiliations

Bidentate ligands formed by self-assembly

Vincent F Slagt et al. Chem Commun (Camb). .

Abstract

A novel supramolecular strategy to prepare bidentate ligands via the assembly of functionalised monomeric ligands on a dimeric zinc(II) porphyrin template is presented; the assembled bidentate ligands show chelating behaviour and their rhodium complexes display enhanced selectivity in the hydroformylation compared to the non-template analogue.

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