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. 2003 Dec 1;42(24):7695-7.
doi: 10.1021/ic030241i.

Structure, reactivity, and computational studies of a novel ruthenium hydrogen sulfide dihydride complex

Sarah L Chatwin  1 , Richard A Diggle, Rodolphe F R Jazzar, Stuart A Macgregor, Mary F Mahon, Michael K Whittlesey
Affiliations

Structure, reactivity, and computational studies of a novel ruthenium hydrogen sulfide dihydride complex

Sarah L Chatwin et al. Inorg Chem. .

Abstract

Addition of 1 atm of H(2)S to [Ru(IMes)(2)(CO)(EtOH)H(2)] (IMes = 1,3-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene) affords the air-stable hydrogen sulfide dihydride complex, [Ru(IMes)(2)(CO)(H(2)S)H(2)] 2. Treatment of 2 with excess H(2)S leads to formation of the 16-electron bis-hydrosulfido complex, [Ru(IMes)(2)(CO)(SH)(2)] 3. Preliminary studies show that 3 reacts with both H(2) and CO in solution as well as in the solid state. Both 2 and 3 have been structurally characterized

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