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. 2004 Jan 7:(1):38-9.
doi: 10.1039/b311268n. Epub 2003 Nov 28.

Practical synthesis of new and highly efficient ligands for the Suzuki reaction of aryl chlorides

Alexander Zapf  1 , Ralf Jackstell, Franck Rataboul, Thomas Riermeier, Axel Monsees, Christa Fuhrmann, Nadim Shaikh, Uwe Dingerdissen, Matthias Beller
Affiliations

Practical synthesis of new and highly efficient ligands for the Suzuki reaction of aryl chlorides

Alexander Zapf et al. Chem Commun (Camb). .

Erratum in

  • Chem Commun (Camb). 2004 Jun 7;(11):1340

Abstract

A practical synthesis of a novel class of phosphine ligands, phosphino substituted N-aryl pyrroles (PAP ligands), has been developed. These ligands are applied in the palladium-catalyzed coupling of a variety of aryl and heteroaryl chlorides with phenylboronic acid showing exceedingly high turnover numbers at mild reaction temperatures and even at room temperature.

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