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. 2004 Jan 7:(1):76-7.
doi: 10.1039/b310956a. Epub 2003 Nov 4.

Relative importance of hydrogen bonding and coordinating groups in modulating the zinc-water acidity

Juan C Mareque-Rivas  1 , Ravi Prabaharan, Rafael Torres Martín de Rosales
Affiliations

Relative importance of hydrogen bonding and coordinating groups in modulating the zinc-water acidity

Juan C Mareque-Rivas et al. Chem Commun (Camb). .

Abstract

The presence of second-sphere -NH(2) groups in the proximity of a zinc(ii)-bound water molecule enhances its acidity by ca. 2 pK(a) units.

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