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. 2004 Feb 21;2(4):443-5.
doi: 10.1039/b316741k. Epub 2004 Jan 28.

Microwave-assisted synthesis of allylic amines: considerable rate acceleration in the hydrozirconation-transmetalation-aldimine addition sequence

Peter Wipf  1 , Jelena Janjic, Corey R J Stephenson
Affiliations

Microwave-assisted synthesis of allylic amines: considerable rate acceleration in the hydrozirconation-transmetalation-aldimine addition sequence

Peter Wipf et al. Org Biomol Chem. .

Abstract

The hydrozirconation of alkynes with zirconocene hydrochloride and the dimethylzinc-mediated addition of alkenylzirconocenes to diphenylphosphinoyl imines can be greatly accelerated with microwave irradiation, resulting in a convenient and rapid one-pot process for the preparation of synthetically useful allylic amines.

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