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. 2004 Feb 18;126(6):1628-9.
doi: 10.1021/ja0390707.

Readily available [2.2.2]-bicyclooctadienes as new chiral ligands for Ir(I): catalytic, kinetic resolution of allyl carbonates

Christian Fischer  1 , Christian Defieber, Takeyuki Suzuki, Erick M Carreira
Affiliations

Readily available [2.2.2]-bicyclooctadienes as new chiral ligands for Ir(I): catalytic, kinetic resolution of allyl carbonates

Christian Fischer et al. J Am Chem Soc. .

Abstract

We report an Ir(I)-catalyzed kinetic resolution of secondary allylic carbonates allowing for their isolation in up to 98% ee. Importantly, the study documents the synthesis and use of a new class of chiral [2.2.2]-bicyclooctadiene ligands for iridium.

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