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. 2004 Feb 19;6(4):481-4.
doi: 10.1021/ol035952z.

Novel functionalized trisubstituted allylboronates via Hosomi-Miyaura borylation of functionalized allyl acetates

P Veeraraghavan Ramachandran  1 , Debarshi Pratihar, Debanjan Biswas, Amit Srivastava, M Venkat Ram Reddy
Affiliations

Novel functionalized trisubstituted allylboronates via Hosomi-Miyaura borylation of functionalized allyl acetates

P Veeraraghavan Ramachandran et al. Org Lett. .

Abstract

[reaction: see text] A series of novel functionalized achiral and chiral allylboronates have been synthesized via the nucleophilic addition of boronates on allyl acetates derived via vinylalumination or Baylis-Hillman reaction of aldehydes. These reagents, upon allylboration with aldehydes, furnish beta-substituted-alpha-methylene-gamma-butyrolactones stereoselectively.

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