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. 2004 Apr 7:(7):878-9.
doi: 10.1039/b400311j. Epub 2004 Mar 4.

A mixed-bridging ligand nonanuclear Ru(II) dendrimer containing a tris- chelating core. Synthesis and redox properties

Julien Leveque  1 , Cécile Moucheron, Andrée Kirsch-De Mesmaeker, Frédérique Loiseau, Scolastica Serroni, Fausto Puntoriero, Sebastiano Campagna, Hélène Nierengarten, Alain Van Dorsselaer
Affiliations

A mixed-bridging ligand nonanuclear Ru(II) dendrimer containing a tris- chelating core. Synthesis and redox properties

Julien Leveque et al. Chem Commun (Camb). .

Abstract

The first ligand-cored dendrimer based on branching Ru(II) centers and containing mixed polypyridine bridging ligands has been prepared; redox experiments suggest that the redox-active core is not reduced at the expected potential, probably as a consequence of shielding induced by the rigid dendritic array.

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