doi: 10.1021/ol049378i.
Efficient and Z-selective cross-metathesis of conjugated enynes
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- PMID: 15176812
- DOI: 10.1021/ol049378i
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Efficient and Z-selective cross-metathesis of conjugated enynes
Org Lett.
.
Abstract
[reaction: see text] The generation of a conjugated alkynyl alkylidene has been achieved using an allyl ether moiety as an intramolecular catalyst delivery vehicle. The reaction of this intermediate with alkenes and alkynes yields conjugated enynes with Z-selectivity.