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. 2004 Jul 7;126(26):8100-1.
doi: 10.1021/ja0483903.

Evidence for a NiI active species in the catalytic cross-coupling of alkyl electrophiles

Thomas J Anderson  1 , Gavin D Jones, David A Vicic
Affiliations

Evidence for a NiI active species in the catalytic cross-coupling of alkyl electrophiles

Thomas J Anderson et al. J Am Chem Soc. .

Erratum in

  • J Am Chem Soc. 2004 Sep 8;126(35):11113

Abstract

Addition of terpyridine to (TMEDA)Ni(CH3)2 results in the high-yield formation of (terpyridyl)NiMe (3). This NiI organometallic complex was found to be capable of transferring its methyl group to iodocyclohexane to produce methylcyclohexane in high yield. Compound 3 can also serve as an initiator for the catalytic cross-coupling of alkyl electrophiles performed under Negishi-like conditions.

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