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. 2004 Jul 7;126(26):8128-9.
doi: 10.1021/ja0475398.

N-Boc-L-valine-connected amidomonophosphane rhodium(I) catalyst for asymmetric arylation of N-tosylarylimines with arylboroxines

Masami Kuriyama  1 , Takahiro Soeta, Xinyu Hao, Qian Chen, Kiyoshi Tomioka
Affiliations

N-Boc-L-valine-connected amidomonophosphane rhodium(I) catalyst for asymmetric arylation of N-tosylarylimines with arylboroxines

Masami Kuriyama et al. J Am Chem Soc. .

Abstract

A catalytic asymmetric arylation of sterically tuned imines with arylboroxines was developed by using N-Boc-l-valine-connected amidomonophosphane rhodium(I) catalyst in n-PrOH. The TMS group used for the steric tuning of imines is convertible to other functionalities that are applicable as a key foothold for the carbon-carbon bond-forming coupling reactions.

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