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. 2004 May 21:(10):1519-20.
doi: 10.1039/b404179h. Epub 2004 Apr 16.

Well-defined indium(III)N-heterocyclic carbene complexes with triflate ligands: structural models for the In(OTf)3 catalyst

Jamie H Cotgreave  1 , David Colclough, Gabriele Kociok-Köhn, Giuseppe Ruggiero, Christopher G Frost, Andrew S Weller
Affiliations

Well-defined indium(III)N-heterocyclic carbene complexes with triflate ligands: structural models for the In(OTf)3 catalyst

Jamie H Cotgreave et al. Dalton Trans. .

Abstract

Reaction of 1,3-dimesitylimidazolium chloride [IMesH]Cl with InMe3 results in (IMes)InMe2Cl, which on treatment with one equivalent of TMS-OTf affords (IMes)InMe2(OTf), which can be converted to the bistriflate complex (IMes)In(Me)(OTf)2 on addition of HOTf.

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