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. 2004 Aug 5;6(16):2821-4.
doi: 10.1021/ol048891t.

Palladium-catalyzed allylalkynylation of benzynes: a highly efficient route to substituted 1-allyl-2-alkynylbenzenes

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Palladium-catalyzed allylalkynylation of benzynes: a highly efficient route to substituted 1-allyl-2-alkynylbenzenes

Masilamani Jeganmohan et al. Org Lett. .

Abstract

Benzynes, generated in situ from 2-(trimethylsilyl)aryl triflates and cesium fluoride, undergo allylalkynylation with allylic chlorides and alkynylstannanes in the presence of palladium catalyst to give 1-allyl-2-alkynylbenzenes in good to excellent yields. [reaction: see text]

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