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. 2004 Aug 21:(16):1854-5.
doi: 10.1039/b406052k. Epub 2004 Jun 30.

Platinum catalysed 3,4- and 1,4-diboration of alpha,beta-unsaturated carbonyl compounds using bis-pinacolatodiboron

Nathan J Bell  1 , Andrew J Cox, Neil R Cameron, John S O Evans, Todd B Marder, Marcel A Duin, Cornelis J Elsevier, Xavier Baucherel, Arran A D Tulloch, Robert P Tooze
Affiliations

Platinum catalysed 3,4- and 1,4-diboration of alpha,beta-unsaturated carbonyl compounds using bis-pinacolatodiboron

Nathan J Bell et al. Chem Commun (Camb). .

Abstract

Bis-pinacolatodiboron reacts with [small alpha],[small beta]-unsaturated carbonyl compounds to give 1,4- and unprecedented 3,4-additions in the presence of a second generation Pt(0) catalyst at ambient temperature.

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