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. 2004 Aug 19;6(17):2933-6.
doi: 10.1021/ol048984a.

Triaryl boron-based A-pi-A vs triaryl nitrogen-based D-pi-D quadrupolar compounds for single- and two-photon excited fluorescence

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Triaryl boron-based A-pi-A vs triaryl nitrogen-based D-pi-D quadrupolar compounds for single- and two-photon excited fluorescence

Zhi-Qiang Liu et al. Org Lett. .

Abstract

Three new A-pi-A-type compounds with trivalent boron, protected by two mesityl groups, as electron acceptor have been synthesized and investigated together with their two diphenylamino-ended D-pi-D analogues. These boranes exhibit large two-photon absorption cross sections and high fluorescence quantum yields.

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