Effects of environment on the creep properties of a poly(ethylmethacrylate) based bone cement

Abstract

The effect of test environment on the creep behavior of a poly(ethylmethacrylate) bone cement was investigated. The aim of the study was to assess the influence of environment on the inherent material behavior, and so it was convenient to perform tests in tension on well-prepared samples. In addition to control tests in air, the liquid environments studied were water, Ringer's solution and Intralipid. Creep tests were performed in each of these environments with a range of aging times, test temperatures and applied stresses. In order to compare the effects of the environments, the creep curves were fitted to a generalized form, from which a creep rate was determined. The ratio of these creep rates between different environments at each testing condition was then used as a basis for a comparison of the detailed effects of environment. It was found that in all cases the water-based environments (water and Ringer's) had similar effects and gave the largest creep rates. Intralipid was then intermediate and air gave the lowest creep rates. These effects are mainly due to plasticization by water, although with Intralipid, some increased monomer leaching occurred, which served to reduce the creep rates. The influence of environment on the effects of aging time, temperature and stress were complex, although in general any conditions which increased water plasticization (longer aging, higher temperature and to a lesser extent, higher stress) gave an increase in creep rate. The major exception to this was at temperatures of 40 degrees C and above, where the effects of water plasticization were diminished, due to the inherent increase in molecular mobility of the material.