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. 2004 Nov 11;6(23):4375-7.
doi: 10.1021/ol0480731.

Highly diastereo- and enantioselective reagents for aldehyde crotylation

Blaine M Hackman  1 , Pamela J Lombardi, James L Leighton
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Highly diastereo- and enantioselective reagents for aldehyde crotylation

Blaine M Hackman et al. Org Lett. .

Abstract

Two new, crystalline solid, storable, and highly enantioselective reagents for aldehyde crotylation have been developed. Both (cis and trans) crotylsilane reagents are easily prepared in bulk, require trivial reaction conditions, and provide the homoallylic alcohol products with near diastereo- and enantiospecificity in many cases.

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