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. 2004 Nov 17;126(45):14736-7.
doi: 10.1021/ja0459781.

Enantioselective sensing of chiral carboxylic acids

Xuefeng Mei  1 , Christian Wolf
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Enantioselective sensing of chiral carboxylic acids

Xuefeng Mei et al. J Am Chem Soc. .

Abstract

A chiral 1,8-diacridylnaphthalene-derived fluorosensor has been prepared and used for enantioselective sensing of a broad variety of chiral carboxylic acids including amino acids, aliphatic acids, arylalkanoic acids, and halogenated carboxylic acids. Fluorescence titration experiments in acetonitrile gave linear Stern-Volmer plots for 1:1 and 1:2 complexes and enantioselectivities up to 4.5.

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