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. 2004 Dec 10;69(25):8963-6.
doi: 10.1021/jo048656o.

Reactivity of phthalimide N-oxyl radical (PINO) toward the phenolic O-H bond. A kinetic study

Enrico Baciocchi  1 , Maria Francesca Gerini, Osvaldo Lanzalunga
Affiliations

Reactivity of phthalimide N-oxyl radical (PINO) toward the phenolic O-H bond. A kinetic study

Enrico Baciocchi et al. J Org Chem. .

Abstract

The reactivity of the phthalimide N-oxyl radical (PINO) toward the OH bond of a series of substituted phenols was kinetically investigated in CH(3)CN. The reaction selectivity and the deuterium kinetic isotope effect were determined. Information on the kinetic solvent effect was also obtained with phenol as the substrate.

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