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. 2004 Dec;60(Pt 12):m631-3.
doi: 10.1107/S0108270104025776. Epub 2004 Nov 11.

Poly[methylammonium tris(mu(2)-formato-kappa2O:O')cobalt(II)]

Miroslav Boca  1 , Ingrid Svoboda, Franz Renz, Hartmut Fuess
Affiliations

Poly[methylammonium tris(mu(2)-formato-kappa2O:O')cobalt(II)]

Miroslav Boca et al. Acta Crystallogr C. 2004 Dec.

Abstract

The structure of the title compound, {(CH(6)N)[Co(CHO(2))(3)]}(n), consists of a three-dimensional net of central Co(II) ions connected via formate (methanediolate) bridges. The negative charge is compensated by protonated methylamine cations. The CoO(6) chromophores form slightly distorted octahedra, which are bridged by C atoms of formate groups. The central Co atom lies on an inversion center and most of the other atoms lie on an m plane.

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