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. 2005 Jan 21:(3):391-3.
doi: 10.1039/b414233k. Epub 2004 Dec 10.

Rh(II) catalysed intramolecular C-H insertion of diazo substrates in water: a simple and efficient approach to catalyst reuse

Nuno R Candeias  1 , Pedro M P Gois, Carlos A M Afonso
Affiliations

Rh(II) catalysed intramolecular C-H insertion of diazo substrates in water: a simple and efficient approach to catalyst reuse

Nuno R Candeias et al. Chem Commun (Camb). .

Erratum in

  • Chem Commun (Camb). 2005 Mar 7;(9):1225

Abstract

Water is an efficient solvent for the Rh2(OAc)4 catalysed intramolecular C-H insertion of a range of diazo substrates without competitive water insertion. Due to the high solubility and stability of the catalyst in water, the catalyst can be efficiently reused.

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