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. 2005 Jan 26;127(3):848-9.
doi: 10.1021/ja043396d.

The total synthesis of gambierol

Henry W B Johnson  1 , Utpal Majumder, Jon D Rainier
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The total synthesis of gambierol

Henry W B Johnson et al. J Am Chem Soc. .

Abstract

This communication describes the total synthesis of the marine polyether toxin, gambierol. This work couples our iterative C-glycoside/enol ether-olefin metathesis strategy to the subunits with a unique olefin metathesis/carbonyl olefination reaction to bring the subunits together.

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