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. 2005 Feb 3;7(3):483-5.
doi: 10.1021/ol0475414.

Silver(I)-catalyzed addition of zirconocenes to glycal epoxides. A new synthesis of alpha-C-glycosides

Peter Wipf  1 , Joshua G Pierce, Nian Zhuang
Affiliations

Silver(I)-catalyzed addition of zirconocenes to glycal epoxides. A new synthesis of alpha-C-glycosides

Peter Wipf et al. Org Lett. .

Abstract

[reaction: see text] Hydrozirconation of terminal alkynes, followed by AgClO4-catalyzed in situ addition of the resultant alkenylzirconocenes to 1,2-anhydrosugars (glycal epoxides) leads to alpha-C-glycosides in moderate to high yields.

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