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. 2005 Feb 28:(8):1085-6.
doi: 10.1039/b415902k. Epub 2005 Jan 12.

Polymer-supported nitroxyl radical catalyst for selective aerobic oxidation of primary alcohols to aldehydes

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Polymer-supported nitroxyl radical catalyst for selective aerobic oxidation of primary alcohols to aldehydes

Michelle Gilhespy et al. Chem Commun (Camb). .

Abstract

PS-TEMPO, a polymer-supported 2,2,6,6-tetramethylpiperidine-N-oxyl (TEMPO), was successfully applied as a recyclable, active and selective catalyst for the oxidation of primary aliphatic and benzylic alcohols to aldehydes by molecular oxygen in the presence of Co(NO3)2 and Mn(NO3)2 as co-catalysts.

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