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. 2005 Mar 17;7(6):1157-60.
doi: 10.1021/ol0500620.

Investigations into the role of ion pairing in reactions of heteroatom-substituted cyclic oxocarbenium ions

Siddhartha R Shenoy  1 , K A Woerpel
Affiliations

Investigations into the role of ion pairing in reactions of heteroatom-substituted cyclic oxocarbenium ions

Siddhartha R Shenoy et al. Org Lett. .

Abstract

[reaction: see text] The O-to-C rearrangement of vinyl acetals is used to demonstrate that tight ion pairing is not involved in the stereoselective nucleophilic addition reactions of alkoxy-substituted cyclic oxocarbenium ions.

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