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. 2005 Apr 15;44(16):2377-9.
doi: 10.1002/anie.200462795.

Metallophosphite-induced nucleophilic acylation of alpha,beta-unsaturated amides: facilitated catalysis by a diastereoselective retro [1,4] Brook rearrangement

Mary R Nahm  1 , Xin Linghu, Justin R Potnick, Christopher M Yates, Peter S White, Jeffrey S Johnson
Affiliations

Metallophosphite-induced nucleophilic acylation of alpha,beta-unsaturated amides: facilitated catalysis by a diastereoselective retro [1,4] Brook rearrangement

Mary R Nahm et al. Angew Chem Int Ed Engl. .

Erratum in

  • Angew Chem Int Ed Engl. 2005 Jul 25;44(30):4660
No abstract available

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Figures

Scheme 1
Scheme 1
Metallophosphite-catalyzed alkene acylation. X=OR, NR2.
Scheme 2
Scheme 2
Functionalization of α-silyl-γ-ketoamides.
Scheme 3
Scheme 3
Enantioselective metallophosphite-catalyzed alkene acylation.
Scheme 4
Scheme 4
Proposed catalytic cycle.
See this image and copyright information in PMC

References

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