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. 2005 May 2;15(9):2239-42.
doi: 10.1016/j.bmcl.2005.03.022.

Observations on the reactivity of thiyl radicals derived from 3,6-epidithiodiketopiperazine-2,5-diones and related congeners

S T Hilton  1 , W B Motherwell, P Potier, C Pradet, D L Selwood
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Observations on the reactivity of thiyl radicals derived from 3,6-epidithiodiketopiperazine-2,5-diones and related congeners

S T Hilton et al. Bioorg Med Chem Lett. .

Abstract

A range of thiyl radicals derived from the reduced form of epidithiodiketopiperazines (ETPs) act as polarity reversal catalysts for the hydrosilylation of an enol lactone but not for H-atom abstraction from a model ribose ester.

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