doi: 10.1021/ja050880n.
Electrostatic control of aromatic stacking interactions
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- PMID: 15954755
- DOI: 10.1021/ja050880n
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Electrostatic control of aromatic stacking interactions
J Am Chem Soc.
.
Abstract
A supramolecular approach has been used to investigate the free energies of intermolecular aromatic stacking interactions. Chemical double mutant cycles have been used to measure the effect of a range of substituents on face-to-face stacking interactions with phenyl and pentafluorophenyl rings. Electrostatic effects dominate the trends in interaction energy.
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