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. 2005 Jun 28:(24):3056-8.
doi: 10.1039/b503239c. Epub 2005 May 6.

Unprecedented use of silver(I) N-heterocyclic carbene complexes for the catalytic preparation of 1,2-bis(boronate) esters

Jesus Ramírez  1 , Rosa Corberán, Mercedes Sanaú, Eduardo Peris, Elena Fernandez
Affiliations

Unprecedented use of silver(I) N-heterocyclic carbene complexes for the catalytic preparation of 1,2-bis(boronate) esters

Jesus Ramírez et al. Chem Commun (Camb). .

Abstract

Catalytic diboration of internal and terminal alkenes with Ag(I) N-heterocyclic carbene complexes leads to 1,2-bis(boronate) esters as single intermediates, that can be oxidised towards the corresponding diols.

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