doi: 10.1039/b504795a.
Epub 2005 May 31.
Easy hydrolysis of white phosphorus coordinated to ruthenium
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- PMID: 15962041
- DOI: 10.1039/b504795a
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Easy hydrolysis of white phosphorus coordinated to ruthenium
Dalton Trans.
.
Abstract
The P4 molecule bound to ruthenium as an eta1-ligand in [CpRu(PPh3)2(eta1-P4)]Y (Y = PF6, CF3SO3) undergoes an easy reaction with water in exceedingly mild conditions to yield PH3, which remains coordinated to the [CpRu(PPh3)2] fragment, and oxygenated derivatives.
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