doi: 10.1016/j.phytochem.2005.05.005.
Biosynthesis of pyrethrin I in seedlings of Chrysanthemum cinerariaefolium
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- PMID: 15964038
- DOI: 10.1016/j.phytochem.2005.05.005
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Biosynthesis of pyrethrin I in seedlings of Chrysanthemum cinerariaefolium
Phytochemistry.
2005 Jul.
Abstract
The biosynthetic pathway to natural pyrethrins in Chrysanthemum cinerariaefolium seedlings was studied using [1-13C]d-glucose as a precursor, with pyrethrin I isolated using HPLC from a leaf extract. The 13C NMR spectrum of pyrethrin I from the precursor-administered seedlings indicated that the acid moiety was biosynthesized from d-glucose via 2-C-methyl-d-erythritol 4-phosphate, whereas the alcohol moiety was possibly biosynthesized from linolenic acid.
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