Intramolecular cyclotrimerization of triynes catalyzed by N-heterocyclic carbene-CoCl2/Zn or -FeCl3/Zn
- PMID: 15987206
- DOI: 10.1021/ol051048q
Intramolecular cyclotrimerization of triynes catalyzed by N-heterocyclic carbene-CoCl2/Zn or -FeCl3/Zn
Abstract
[reaction: see text] Triynes 1 could effectively be cyclotrimerized to annulated benzenes 2 by treatment with a catalytic amount of zinc powder, N-heterocyclic carbene, and CoCl(2) or FeCl(3).
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