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. 2005 Aug 7:(29):3661-3.
doi: 10.1039/b503708e. Epub 2005 Jun 10.

Encapsulated transition metal catalysts comprising peripheral Zn(II)salen building blocks: template-controlled reactivity and selectivity in hydroformylation catalysis

Arjan W Kleij  1 , Martin Lutz, Anthony L Spek, Piet W N M van Leeuwen, Joost N H Reek
Affiliations

Encapsulated transition metal catalysts comprising peripheral Zn(II)salen building blocks: template-controlled reactivity and selectivity in hydroformylation catalysis

Arjan W Kleij et al. Chem Commun (Camb). .

Abstract

Encapsulated phosphane ligands can be easily constructed through coordinative interactions between Zn(II)-salphen complexes and pyridylphosphane templates; the template has a pronounced impact on the catalyst structure and consequently on the performance in the hydroformylation of 1-octene.

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