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. 1999 Sep 9;1(5):773-4.
doi: 10.1021/ol9907567.

Stereospecificity and mechanism in cation radical Diels-Alder and cyclobutanation reactions

N L Bauld  1 , J Yang
Affiliations

Stereospecificity and mechanism in cation radical Diels-Alder and cyclobutanation reactions

N L Bauld et al. Org Lett. .

Abstract

[reaction: see text] The cation radical Diels-Alder and cyclobutanation reactions of cis- and trans-1,2-(diaryloxy)ethenes with a cyclic and an acyclic diene have been found to be stereospecific, in accord with a concerted cycloaddition mechanism.

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