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. 2005 Sep 21:(18):2982-4.
doi: 10.1039/b508192k. Epub 2005 Aug 4.

Alpha,beta-(C-C-C) agostic bonds in transition metal based olefin metathesis catalyses

Cherumuttathu H Suresh  1 , Mu-Hyun Baik
Affiliations

Alpha,beta-(C-C-C) agostic bonds in transition metal based olefin metathesis catalyses

Cherumuttathu H Suresh et al. Dalton Trans. .

Abstract

An alpha,beta-(C-C-C) agostic bond is found to provide the additional stabilization needed to make the formally 14-electron metallacyclobutane intermediate lower in energy than its 16-electron alkylidene analogue during olefin metathesis catalysis.

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