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. 2005 Sep 15;7(19):4249-52.
doi: 10.1021/ol0517473.

Cobalt-catalyzed hydrohydrazination of dienes and enynes: access to allylic and propargylic hydrazides

Jérôme Waser  1 , José C González-Gómez, Hisanori Nambu, Pascal Huber, Erick M Carreira
Affiliations

Cobalt-catalyzed hydrohydrazination of dienes and enynes: access to allylic and propargylic hydrazides

Jérôme Waser et al. Org Lett. .

Abstract

[reaction: see text] The cobalt-catalyzed hydrohydrazination reaction of dienes and enynes is presented. Allylic and propargylic hydrazines were obtained in synthetically useful yields (allylic amines, 60-90%; propargylic amines, 47-83%) and good chemo- and regioselectivity.

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