doi: 10.1021/ja054079p.
Intermolecular C-N addition of amides and S-N addition of sulfinamides to arynes
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- PMID: 16173716
- DOI: 10.1021/ja054079p
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Intermolecular C-N addition of amides and S-N addition of sulfinamides to arynes
J Am Chem Soc.
.
Abstract
An efficient, mild, transition-metal-free method has been developed for the intermolecular C-N sigma-bond addition of amides and S-N sigma-bond addition of sulfinamides to arynes to form one C-C bond and one heteroatom-carbon bond in one step at room temperature. Evidence for a stepwise mechanism is provided.
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