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. 2005 Sep 28;127(38):13112-3.
doi: 10.1021/ja054079p.

Intermolecular C-N addition of amides and S-N addition of sulfinamides to arynes

Zhijian Liu  1 , Richard C Larock
Affiliations

Intermolecular C-N addition of amides and S-N addition of sulfinamides to arynes

Zhijian Liu et al. J Am Chem Soc. .

Abstract

An efficient, mild, transition-metal-free method has been developed for the intermolecular C-N sigma-bond addition of amides and S-N sigma-bond addition of sulfinamides to arynes to form one C-C bond and one heteroatom-carbon bond in one step at room temperature. Evidence for a stepwise mechanism is provided.

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