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. 2005 Oct 21:(39):4961-3.
doi: 10.1039/b508142d. Epub 2005 Sep 8.

Enantioselective construction of stereogenic quaternary centres via Rh-catalyzed asymmetric addition of alkenylboronic acids to alpha,beta-unsaturated pyridylsulfones

Pablo Mauleón  1 , Juan C Carretero
Affiliations

Enantioselective construction of stereogenic quaternary centres via Rh-catalyzed asymmetric addition of alkenylboronic acids to alpha,beta-unsaturated pyridylsulfones

Pablo Mauleón et al. Chem Commun (Camb). .

Abstract

The highly enantioselective construction of all-carbon quaternary stereogenic centres via Rh-catalyzed Chiraphos-mediated conjugate addition of alkenylboronic acids to beta,beta-disubstituted alpha,beta-unsaturated 2-pyridylsulfones is described.

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