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. 2005 Nov 7:(41):5175-7.
doi: 10.1039/b509678b. Epub 2005 Sep 29.

Tuneable asymmetric copper-catalysed allylic amination and oxidation reactions

J Stephen Clark  1 , Caroline Roche
Affiliations

Tuneable asymmetric copper-catalysed allylic amination and oxidation reactions

J Stephen Clark et al. Chem Commun (Camb). .

Abstract

Asymmetric allylic amination or oxidation can be achieved by reaction of an alkene with a peroxycarbamate catalysed by a chiral copper bis-oxazoline complex, and the reaction can be tuned to give either the amination or oxidation product by reagent choice.

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